{"id":34279,"date":"2024-07-03T11:00:17","date_gmt":"2024-07-03T09:00:17","guid":{"rendered":"https:\/\/resoilfoundation.org\/?p=34279"},"modified":"2024-07-12T11:02:39","modified_gmt":"2024-07-12T09:02:39","slug":"australia-decontamination-fluorine-pfas","status":"publish","type":"post","link":"https:\/\/resoilfoundation.org\/en\/innovation-technology\/australia-decontamination-fluorine-pfas\/","title":{"rendered":"Australian researchers tested a new method for PFAS decontamination"},"content":{"rendered":"<h2>Researchers at the University of New South Wales in Sydney have developed an effective technique to break down the strong carbon-fluorine bonds that make PFAS hard to break do<\/h2>\n<p style=\"text-align: center;\">by Matteo Cavallito<\/p>\n<p>&nbsp;<\/p>\n<p>Perfluoroalkylated substances or <strong>PFAS<\/strong> <a href=\"https:\/\/resoilfoundation.org\/en\/articles\/contamination-fluorine-soil-research-pfas\/\" target=\"_blank\" rel=\"noopener\">are known<\/a> to be a <strong>serious threat to soils<\/strong>. Particularly persistent in soils, in fact, these compounds are difficult to remove to the point of being a real obstacle in environmental restoration. A group of researchers from the <strong>University of New South Wales in Sydney<\/strong>, however, may have found a solution to the problem.<\/p>\n<p>The scientists, says a <a href=\"https:\/\/www.unsw.edu.au\/newsroom\/news\/2024\/06\/new-method-to-degrade-pfas-forever-chemicals-found-effective-in-the-lab\" target=\"_blank\" rel=\"noopener\">statement<\/a>, have in fact designed a <strong>catalyst<\/strong> system capable of triggering a reaction to break down the most common branched PFAS. &#8220;Owing to its robust nature, simple application, and cost effectiveness, the new system we have developed shows successful remediation in the lab, which we hope to eventually test at a larger scale,&#8221; said <strong>Jun Sun<\/strong>, researcher and co-author of the <a href=\"https:\/\/www.sciencedirect.com\/science\/article\/pii\/S0043135424007048\" target=\"_blank\" rel=\"noopener\">study<\/a> published in the journal Water Research. The new method, the scientists claim, would pave the way for more efficient and sustainable remediation in the future.<\/p>\n<div class='avia-iframe-wrap'>\n<blockquote class=\"wp-embedded-content\" data-secret=\"r0YAGdvS27\"><p><a href=\"https:\/\/resoilfoundation.org\/en\/articles\/fluoride-contamination-otters\/\">Fluoride contamination affects British otters<\/a><\/p><\/blockquote>\n<p><iframe loading=\"lazy\" class=\"wp-embedded-content\" sandbox=\"allow-scripts\" security=\"restricted\" style=\"position: absolute; clip: rect(1px, 1px, 1px, 1px);\" title=\"&#8220;Fluoride contamination affects British otters&#8221; &#8212; Re Soil Foundation\" src=\"https:\/\/resoilfoundation.org\/en\/articles\/fluoride-contamination-otters\/embed\/#?secret=8tgXxUHYoa#?secret=r0YAGdvS27\" data-secret=\"r0YAGdvS27\" width=\"600\" height=\"338\" frameborder=\"0\" marginwidth=\"0\" marginheight=\"0\" scrolling=\"no\"><\/iframe><\/div>\n<h5>The characteristics of PFAS<\/h5>\n<p>Not surprisingly called forever chemicals because of <strong>their persistence in soils<\/strong>, PFAS &#8220;are both highly stable and useful in products designed to repel grease and water but it also means they do not readily biodegrade,&#8221; <a href=\"https:\/\/www.scientificamerican.com\/article\/pesticides-are-spreading-toxic-lsquo-forever-chemicals-rsquo-scientists-warn\/\" target=\"_blank\" rel=\"noopener\">wrote<\/a>\u00a0the journal Scientific American. These compounds are typically found in <strong>fluorinated pesticides<\/strong> (i.e. those containing one or more fluorine atoms in their molecular structure) that are considered particularly effective in combating plant <strong>pests<\/strong>.<\/p>\n<blockquote><p>This efficacy derives precisely from the chemical stability that favours their prolonged action. A characteristic which brings with it the obvious downside: the difficulty of disposal.<\/p><\/blockquote>\n<p>According to some <a href=\"https:\/\/resoilfoundation.org\/en\/articles\/flourinated-pesticides-health-environment\/\" target=\"_blank\" rel=\"noopener\">estimates<\/a>, the half-life of some fluorinated products &#8211; that is, the time it takes for their presence in the environment to be halved after spraying &#8211; can be up to <strong>two and a half years<\/strong>. According to the EPA, the US Environmental Protection Agency, pollutants are defined as &#8216;persistent&#8217; when they have a half-life of more than 60 days.<\/p>\n<div class='avia-iframe-wrap'>\n<blockquote class=\"wp-embedded-content\" data-secret=\"SIUQJtB02g\"><p><a href=\"https:\/\/resoilfoundation.org\/en\/articles\/flourinated-pesticides-health-environment\/\">Flour-based pesticides hit the market as scientists are concerned<\/a><\/p><\/blockquote>\n<p><iframe loading=\"lazy\" class=\"wp-embedded-content\" sandbox=\"allow-scripts\" security=\"restricted\" style=\"position: absolute; clip: rect(1px, 1px, 1px, 1px);\" title=\"&#8220;Flour-based pesticides hit the market as scientists are concerned&#8221; &#8212; Re Soil Foundation\" src=\"https:\/\/resoilfoundation.org\/en\/articles\/flourinated-pesticides-health-environment\/embed\/#?secret=WVY5lkqzNv#?secret=SIUQJtB02g\" data-secret=\"SIUQJtB02g\" width=\"600\" height=\"338\" frameborder=\"0\" marginwidth=\"0\" marginheight=\"0\" scrolling=\"no\"><\/iframe><\/div>\n<h5>The solution? Zero-valent nano-metals<\/h5>\n<p>From a technical point of view, experts explain, the main problem with PFAS is the <strong>difficulty of breaking the strong carbon-fluorine bonds<\/strong> that characterise them at the molecular level. One of the most widely used remediation methods involves the use of activated carbon to absorb these substances. Another technique involves the use of a strong oxidising agent to separate the substance. However, both methods are challenging, not entirely effective and not very sustainable.<\/p>\n<blockquote><p>To solve these problems, the authors chose to focus on so-called <strong>zero-valent nano-metals<\/strong> (nZVMs).<\/p><\/blockquote>\n<p>These particular chemical agents, the study explains,&#8221;have been extensively utilized for decades in the reductive remediation of groundwater contaminated with chlorinated organic compounds, owing to their robust reducing capabilities, simple application, and cost-effectiveness.&#8221; However, &#8220;there remains a dearth of information regarding the efficient reductive defluorination of linear or branched per- and polyfluoroalkyl substances (PFASs) using nZVMs as reductants, largely due to the absence of appropriate catalysts.&#8221; And it is precisely on this aspect that the researchers&#8217; work has focused.<\/p>\n<div class='avia-iframe-wrap'>\n<blockquote class=\"wp-embedded-content\" data-secret=\"u7FMG5ZNFh\"><p><a href=\"https:\/\/resoilfoundation.org\/en\/articles\/ball-milling-soil-fluoride\/\">Ball milling cleans soil of persistent fluoride<\/a><\/p><\/blockquote>\n<p><iframe loading=\"lazy\" class=\"wp-embedded-content\" sandbox=\"allow-scripts\" security=\"restricted\" style=\"position: absolute; clip: rect(1px, 1px, 1px, 1px);\" title=\"&#8220;Ball milling cleans soil of persistent fluoride&#8221; &#8212; Re Soil Foundation\" src=\"https:\/\/resoilfoundation.org\/en\/articles\/ball-milling-soil-fluoride\/embed\/#?secret=PoZ9dFIJtF#?secret=u7FMG5ZNFh\" data-secret=\"u7FMG5ZNFh\" width=\"600\" height=\"338\" frameborder=\"0\" marginwidth=\"0\" marginheight=\"0\" scrolling=\"no\"><\/iframe><\/div>\n<h5>A much more effective technique<\/h5>\n<p>Catalysts are all those substances that are capable of triggering a chemical reaction. These include vitamin B12, a popular compound capable of triggering the reaction between nano-metals and PFAS. Its use, however, does not appear satisfactory: the triggering process is slow and ineffective. Therefore, the researchers chose to synthesise a catalyst that mirrors the ring shape of B12: <strong>cobalt porphyrin<\/strong>.<\/p>\n<blockquote><p>The authors tested the method by measuring <strong>the amount of fluoride<\/strong> (the salt of hydrofluoric acid, ed.) released by breaking carbon-fluorine bonds.<\/p><\/blockquote>\n<p>They found that in the space of five hours, porphyrin <strong>caused 75% of the amount of the element to be released<\/strong>. At the same time, the amount released with B12 was no more than 8%. The effectiveness of the system, in short, is evident. And the hope of the researchers is that the method can be used in future remediation actions.<\/p>\n","protected":false},"excerpt":{"rendered":"<p>Researchers at the University of New South Wales in Sydney have developed an effective technique to break down the strong carbon-fluorine bonds that make PFAS hard to break do<\/p>\n","protected":false},"author":4,"featured_media":34282,"comment_status":"closed","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[152,134],"tags":[153,220,314,237,188,186],"class_list":["post-34279","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-innovation-technology","category-articles","tag-best-practice-en","tag-carbon","tag-contaminazione-en","tag-organic-matter","tag-research","tag-soil"],"yoast_head":"<!-- This site is optimized with the Yoast SEO plugin v27.4 - https:\/\/yoast.com\/product\/yoast-seo-wordpress\/ -->\n<title>Australian researchers tested a new method for PFAS remediation<\/title>\n<meta name=\"description\" content=\"The use of cobalt porphyrin which is a synthetic catalyst is crucial for the effective breakdown of PFAS. the study says\" \/>\n<meta name=\"robots\" content=\"index, follow, max-snippet:-1, max-image-preview:large, max-video-preview:-1\" \/>\n<link rel=\"canonical\" href=\"https:\/\/resoilfoundation.org\/en\/innovation-technology\/australia-decontamination-fluorine-pfas\/\" \/>\n<meta property=\"og:locale\" content=\"en_US\" \/>\n<meta property=\"og:type\" content=\"article\" \/>\n<meta property=\"og:title\" content=\"Australian researchers tested a new method for PFAS remediation\" \/>\n<meta property=\"og:description\" content=\"The use of cobalt porphyrin which is a synthetic catalyst is crucial for the effective breakdown of PFAS. the study says\" \/>\n<meta property=\"og:url\" content=\"https:\/\/resoilfoundation.org\/en\/innovation-technology\/australia-decontamination-fluorine-pfas\/\" \/>\n<meta property=\"og:site_name\" content=\"Re Soil Foundation\" \/>\n<meta property=\"article:publisher\" content=\"https:\/\/www.facebook.com\/resoilfoundation\/\" \/>\n<meta property=\"article:published_time\" content=\"2024-07-03T09:00:17+00:00\" \/>\n<meta property=\"article:modified_time\" content=\"2024-07-12T09:02:39+00:00\" \/>\n<meta property=\"og:image\" content=\"https:\/\/resoilfoundation.org\/wp-content\/uploads\/2024\/07\/PFAS-1.jpg\" \/>\n\t<meta property=\"og:image:width\" content=\"800\" \/>\n\t<meta property=\"og:image:height\" content=\"600\" \/>\n\t<meta property=\"og:image:type\" content=\"image\/jpeg\" \/>\n<meta name=\"author\" content=\"Matteo Cavallito\" \/>\n<meta name=\"twitter:card\" content=\"summary_large_image\" \/>\n<meta name=\"twitter:creator\" content=\"@re_soil\" \/>\n<meta name=\"twitter:site\" content=\"@re_soil\" \/>\n<meta name=\"twitter:label1\" content=\"Written by\" \/>\n\t<meta name=\"twitter:data1\" content=\"Matteo Cavallito\" \/>\n<script type=\"application\/ld+json\" class=\"yoast-schema-graph\">{\"@context\":\"https:\\\/\\\/schema.org\",\"@graph\":[{\"@type\":\"Article\",\"@id\":\"https:\\\/\\\/resoilfoundation.org\\\/en\\\/innovation-technology\\\/australia-decontamination-fluorine-pfas\\\/#article\",\"isPartOf\":{\"@id\":\"https:\\\/\\\/resoilfoundation.org\\\/en\\\/innovation-technology\\\/australia-decontamination-fluorine-pfas\\\/\"},\"author\":{\"name\":\"Matteo Cavallito\",\"@id\":\"https:\\\/\\\/resoilfoundation.org\\\/en\\\/#\\\/schema\\\/person\\\/9deaff5320c99714a3a7944e4b7c8fbe\"},\"headline\":\"Australian researchers tested a new method for PFAS decontamination\",\"datePublished\":\"2024-07-03T09:00:17+00:00\",\"dateModified\":\"2024-07-12T09:02:39+00:00\",\"mainEntityOfPage\":{\"@id\":\"https:\\\/\\\/resoilfoundation.org\\\/en\\\/innovation-technology\\\/australia-decontamination-fluorine-pfas\\\/\"},\"wordCount\":687,\"image\":{\"@id\":\"https:\\\/\\\/resoilfoundation.org\\\/en\\\/innovation-technology\\\/australia-decontamination-fluorine-pfas\\\/#primaryimage\"},\"thumbnailUrl\":\"https:\\\/\\\/resoilfoundation.org\\\/wp-content\\\/uploads\\\/2024\\\/07\\\/PFAS-1.jpg\",\"keywords\":[\"best practice\",\"carbon\",\"contaminazione\",\"organic matter\",\"research\",\"soil\"],\"articleSection\":[\"Innovation &amp; 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